Current carbon capture schemes are not really ready for prime time, plagued by toxicity, corrosiveness and inefficiency, but a team of chemists have invented low-toxicity, highly effective carbon-trapping "sponges" that could lead to increased use of the technology.
Used in natural gas and coal-burning plants, the most common carbon capture method today is called amine scrubbing, in which post-combustion, carbon dioxide-containing flue gas passes through liquid vats of amino compounds, or amines, which absorb most of the carbon dioxide. The carbon-rich gas is then pumped away - sequestered - or reused. The amine solution is extremely corrosive and requires capital-intensive containment.
A research team led by Emmanuel Giannelis, the Walter R. Read Professor of Engineering in the Department of Materials Science and Engineering, has invented a powder that performs as well or better than industry benchmarks for carbon capture.
It consists of a silica scaffold, the sorbent support, with nanoscale pores for maximum surface area. They dip the scaffold into liquid amine, which soaks into the support like a sponge and partially hardens. The finished product is a stable, dry white powder that captures carbon dioxide even in the presence of moisture.
Solid amine sorbents are used in carbon capture, Giannelis said, but the supports are usually only physically impregnated with the amines. Over time some of the amine is lost, decreasing effectiveness and increasing cost.
The researchers instead grew their amine onto the sorbent surface, which causes the amine to chemically bond to the sorbents, meaning very little amine loss over time.
Qi said the next steps are to optimize the sorbent and to eventually demonstrate it for industry, possibly at Cornell for retrofitting its power plant. He also said the technology could be used on smaller scale - for example, in greenhouses, where the captured carbon
Source: Cornell University