Current strict environmental legislation demands advanced concepts to reduce the emission of harmful gasses by cars. Reducing the emission of nitrous oxides (NOx) emitted by diesel and lean-burn petrol engines is one of the challenges faced.

These economical engines produce exhaust fumes that are particularly rich in oxygen and therefore the conventional three-way catalytic converter is not suitable for converting the generated NOx into nitrogen. The current trend is therefore to add specific components such as barium to the catalytic converter to store the NOx formed.

Dutch researcher Karen Scholz has taken a careful look at the properties of a new type of catalytic converter. For this so-called NOx Storage Reduction (NSR) catalytic converter the fuel is alternately combusted in the engine under oxygen-rich (lean) and fuel-rich (rich) conditions. Such diesel engines and 'lean-burn' petrol engines are more economical than conventional engines.

In this new type of NOx Storage Reduction (NSR) catalytic converter the diesel or petrol combustion in the engine takes place alternately over long oxygen-rich and short fuel-rich periods. During a long oxygen-rich period the generated NOx is stored in the barium component. When this component becomes saturated the catalyst is regenerated. This happens during the short fuel-rich period when an oxygen-poor emission gas is produced. The NOx stored is released and subsequently reduced to nitrogen over a precious metal such as platinum. Scholz investigated this NSR mechanism to gain a better understanding of how the storage component functions during the oxygen-rich and fuel-rich periods.

The researcher carried out experiments in a laboratory reactor containing the NSR catalyst. She studied the behaviour of the catalyst in detail, including analysis of the effect of the various forms in which barium occurs in the catalytic converter, the effect of the presence of carbon dioxide and water in the exhaust gas, and the effect of the various reducing agents, such as carbon monoxide, hydrogen, and ethylene on the NOx storage and reduction. The research has yielded important new insights with respect to the function of various components in the catalytic converter. Scholz has also produced a practical mathematical model that describes the various chemical reactions in the catalytic converter.

Using this reaction model, a regulatory system in the car can determine when the maximum NOx capacity of the catalyst has been reached, followed by the length of time extra fuel must be injected to regenerate the catalyst. The research was carried out in cooperation with the car manufacturers PSA Peugeot Citroen, Toyota and Ford, the car development company PD&E Automotive Solutions, catalytic converter manufacturer Engelhard De Meern (now BASF), and with TNO Automotive, Shell, E.P. Controls and IPCOS.

Source: Netherlands Organization for Scientific Research