Wind tunnel experiments to determine the role of asymmetry caused by the orientation of a volleyball on its aerodynamic characteristics found that
it would be easy to make a volleyball more predictable; with a hexagonal or dimpled pattern instead of six panels, each made with three parallel rectangular strips - but that would eliminate some of the fun.
Aerodynamics, the behavior of air as it flows around objects, plays a huge role in volleyball, golf, baseball, tennis, and soccer.
Aerodynamics is why soccer players like David Beckham could "bend" kicks into the goal, and why baseball pitchers throw knuckleballs that can dance around an opposing player's bat.