Though the trend has been to listen to environmental claims about the benefits of trees in cities, in science they have a well-established dark side: in urban cities, they produce a lot of ground-level ozone, the very thing environmentalists spent decades lobbying against.
During hot days, trees emit compounds that worsen ozone, such as formaldehyde, which forms from isoprene, a volatile organic compound that trees can give off when temperatures are hot, and
terpenes, which also interact with sunlight to create a "natural" smog. If you have witnessed the haze of the Great Smoky Mountains, you are breathing in natural pollution.