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    Dye sensitized solar cell
    By Mei Fang | January 24th 2011 06:21 AM | 3 comments | Print | E-mail | Track Comments
    Mei
    About Mei

    Ph.D student in Engineering Material Physics, Royal Institute of Technology, Sweden. 2006-2008 Master's degree in Material Science, Central South...

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    An introduction of Dye sensitized solar cell Energy resources: As we know there are some ways to get energy so that electrical can be generated, like fossil fuel, solar power, nuclear power, wind power, tidal power, geothermal power etc.1 In all these resources, fossil fuel (including coal, oil and gas) has contributed a lot in the history, and even nowadays, it is the major energy resource for human being. However, this is not a renewable energy resource, and products from the burning of fossil fuel contribute to the pollution of the atmosphere. For the developments of our next generation, renewable and environment protective energy resources need to be developed. Solar power: Among all the clean energy resources, solar power is the most powerful energy resource. It was said if people can harness properly, the energy from solar to the earth in one minutes can be enough to meet human’s demands for one year! This powerful energy supply should not only be used in drying clothes, or heating water! Thanks to Becquerel, the discovery of photovoltaic effect makes it possible to create electrical from sun light.2 The first solar cell was then built by Charles Fritts in 1883 with 1% efficient.3 With the development of solar cell in last century, the efficient can be 42.4% in nowadays.3 However, the cost of the high efficiency cell make it uncompetitive with the traditional energy source. Low-cost solar cell was developed in 1990s as the third generation of solar cell: the dye sensitized solar cell. Dye Sensitized Solar Cell (DSSC): DSSC is a class of low-cost solar cell based on a semiconductor layer between a photo-sensitized anode and an electrolyte, invented by Michael Grätzel and Brian O’ Regan in 1991.4 It is technically attractive because of the low-cost raw materials and the simple manufacture process.5 A DSSC is constructed by a transparent electrode (usually ITO glass), a dye sensitized semiconductor layer (TiO2 particles surrounded by dye), an electrolyte (iodine ionic solution) and a counter electrode. The sunlight goes through the transparent electrode and captured by the dye sensitized semiconductor layer, of which the electrons in the valence band are excited into conduct band. The electrons are then transported to the counter electrode through the electrolyte and therefore photo-voltage and photo-currents are created in the cell. The reported efficiency of DSSC can reach 11%, much lower than the reported efficiency of traditional Si solar cell of 42%, but its cost is about 1/10 of a Si solar cell. Besides, a DSSC can even be used in room with low requirement of light. References: 1 Alternativeenergy, (2010), p. http://www.darvill.clara.net/altenerg/index.htm. 2 Wikipedia, (2011), p. http://en.wikipedia.org/wiki/Photovoltaic_effect. 3 Wikipedia, (2011), p. http://en.wikipedia.org/wiki/Solar_cell. 4 Wikipedia, (2011), p. http://en.wikipedia.org/wiki/Dye-sensitized_solar_cell. 5 Energyer, (2005-2009), p. http://www.energyer.com/Know_How/dye-sensitized-solar-cell.html.

    Comments

    Bonny Bonobo alias Brat
    Thanks Mei for this very interesting article. I followed your reference to Wikipedia which said that
    The major disadvantage to the Dye Sensitive Solar Cell (DSSC) design is the use of the liquid electrolyte, which has temperature stability problems. At low temperatures the electrolyte can freeze, ending power production and potentially leading to physical damage. Higher temperatures cause the liquid to expand, making sealing the panels a serious problem.

    Another major drawback is the electrolyte solution, which contains volatile organic solvents and must be carefully sealed. This, along with the fact that the solvents permeate plastics, has precluded large-scale outdoor application and integration into flexible structure.[16]Replacing the liquid electrolyte with a solid has been a major ongoing field of research. Recent experiments using solidified melted salts have shown some promise, but currently suffer from higher degradation during continued operation, and are not flexible.

    I wondered if you knew about how the latest progressions in overcoming these obstacle are going?
    Make love not war
    Hi Helen,

    We has tried some solid electrolyte, unfortunately the efficiency is very low. Now we focused on liquid electrolyte, trying to increase the viscosity of the liquid, and it seems the stablility of the DSSC have been improved.

    csumsefm
    The photons with energy less than the band gap energy makes no contribution to the output of the solar cell, and the ones with greater energy than the band gap energy contribute to the cell output, but the extra energy is wasted as heat. Therefore energy conversion efficicency is used to characterized the performance of the solar cell. To improve the efficiency, composite semiconductors can be used to form heterostrucutre and provide interfacial charge transfer between the components.